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------=_NextPart_01C6C112.F674F530 Content-Location: file:///C:/2D27B0F3/Physics222Solids_files/master07.xml Content-Transfer-Encoding: quoted-printable Content-Type: text/xml; charset="utf-8" ------=_NextPart_01C6C112.F674F530 Content-Location: file:///C:/2D27B0F3/Physics222Solids_files/pres.xml Content-Transfer-Encoding: quoted-printable Content-Type: text/xml; charset="utf-8" ------=_NextPart_01C6C112.F674F530 Content-Location: file:///C:/2D27B0F3/Physics222Solids_files/slide0197.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Slide 1
Solids: Amorphous vs. Crystalline
•Amorphous
&= #8211;Glass, plastic...
&= #8211;No sharp “phase transition”
&= #8211;“Supercooled”
•Annealing
&= #8211;Spin glasses
– <= /div>
–
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Solids: Amorphous vs. Crystalline
•Crystalline
–<= /span>Microscopic Order
–<= /span>Sharp phase transition
•All “next neighbor” interactions are t= he same
–<= /span>Defects
•point defects
•edge dislocation
–<= /span>provides ductility
–<= /span>Work hardening
–<= /span>Annealing
•screw dislocation
–
–
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Ionic Crystals
•Same mechanism as ionic molecules, but more neighbors...
•
•Ionization energy & electron affinity + attrac= tion + Fermi repulsion
•
•cohesive energy
–<= /span>Energy/atom to separate crystal into individual atoms.
–
•Madelung constants
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Thought Question
•If I have a positive and a negative ion, how close= do = they want to be together?
–A: They want to = be right on top of each other.
–B: They want to = be as far away as possible.
–C: They want to = be about one nuclear radius apart.
–D: They want to = be about one electron orbital radius apart.
–E: They want to = be three Book of Mormons apart.
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Optical / Electrical properties
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Covalent Crystals
<= span class=3DBB style=3D'position:absolute;left:-4.43%;top:-.15em'>•Strongest Bonds
<= span style=3D'visibility:hidden'>•
•Just like covalent molecules, but bigger!
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Hydrogen Bonds
<= span style=3D'font-size:88%'>• They are weaker than bonds within molecules
• They are still very important
–<= span style=3D'mso-spacerun:yes'> Surface tension in water
–<= span style=3D'mso-spacerun:yes'> Ice
–<= span style=3D'mso-spacerun:yes'> DNA
Permanent dipole moments = --- repel and attract like little magnets (only
it’s really an e= lectric dipole)
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Thought Question
•How does the dipole-dipole interaction potential energy U(r) fal= l off with the distance r for two molecules if only = one has a permanent dipole moment?
R= 11;A: 1/r3 B: 1/r4 C: 1/r6 
R= 11;
R= 11;D. There is no interaction potential: U=3D0 = for all r. = ;
R= 11;E: None of the above
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Dipole-Dipole (van der Waals) Bonds
if only one of the two molecules has a permanent = dipole moment
Shorter range, even weaker than hydrogen bonds
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Thought Question
•How does the dipole-dipole interaction potential energy U(<= i>r) fall off with the distance r for two molecules if neither has a permanent dipole moment?
R= 11;   A: 1/r3  B: 1/r6 = C: 1/r9<= br> <= br> D: 1/r12  E: There is no potential, si= lly!
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Thought Question
•Which of the following bond is the weakest?
R= 11;A : Covalent
R= 11;B : Ionic
R= 11;C : van der Waals
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Polymers
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