Selection Rules for Electric Dipole Radiation
1. ΔL = 0 (usually not), ± 1, but Δl = ± 1 for the e- involved.
2. ΔS = 0, multiplicity does not change.
3. ΔJ = 0, ± 1, except J = 0 → J = 0.
4. Δl = ± 1, only one electron jumps, (for the Russell-Saunders coupling). Hence parity must
change.5. ΔMJ = 0, ± 1, except 0 → 0 iff ΔJ = 0.