Evolution of the Earth's Atmosphere

Stage Time [yrs] of first occurrence Duration [yrs] Description
 Original

 - 4.6 ´ 109 yrs

 Earth formation time
~ 108 yrs

 Earth formed (see also 2 and 3) in the inner solar system where gases and
 ices were scarce.  Refractory materials (mostly minerals) dominated.
 Hence the nascent earth had a sparse atmosphere, probably just a tenuous
 layer of H, He, and H-rich gases such as H2, NH3 and CH
4.  This atmo-
 sphere was soon lost as it escaped into space because of the high surface
 temperature of the young earth and the lightness of these molecules.
 Outgassing &
 Accretion
(Ahrens doesn't even mention accretion, but some experts believe it may have been as important as outgassing in contributing to the atmosphere.)

 Since formation, but acquired mostly in first
few ´ 108 yrs

 Volcanic eruptions have added much CO2, H2O and N2 and lesser
 amounts of other gases.  Cometary impacts have added ices of CO2,
 H2O, NH3 and CH
4 which immediately vaporized to become part of the
 atmosphere.  Photodissociation of these last three molecules as well as
 volcanically produced H2O increased atmospheric H, O, N and C.  Most
 of the H escaped while chemically active O combined with other atoms
 to form a little O2, but more H2O and more CO2.  As time passed most
 of the H2O condensed out of the atmosphere to form oceans.  Much of
 the CO2 dissolved in the ocean and eventually was deposited in
 sedimentary carbonate rocks such as limestone or metamorphic rocks
 such as marble (metamorphosed limestone).  This left N2 as the principal
 atmospheric molecule.
 Photosynthesis

-3 to -2 ´ 109 yrs

 From onset until present

 The first atmospheric O2 may have formed as described in the box above,
 but, with the development of plant life, photosynthesis began to add O2 to
 the atmosphere at a much greater rate, building to essentially the current
 O2 concentration several ´ 108 years ago.